Gas-phase complexation of polyethers with halide ions
نویسندگان
چکیده
منابع مشابه
Phase determination using halide ions.
A short soak of protein crystals in cryosolution containing bromides or iodides leads to incorporation of these ions into the ordered solvent shell around the protein surface. The halide ions display significant anomalous signal, bromides in the vicinity of the absorption edge at 0.92 A, and iodides at longer wavelengths, e.g., provided by the copper sources. Bromides can, therefore, be used th...
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Complexation of [UO2](2+) with Cl(-), Br(-), and I(-) in N,N-dimethylformamide (DMF) was studied by UV-vis absorption spectroscopy and extended X-ray absorption fine structure (EXAFS) to clearly differentiate halide coordination strengths to [UO2](2+). In the Cl(-) system, it was clarified that the Cl(-) coordination to [UO2](2+) in DMF proceeds almost quantitatively. The coordination number of...
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Singly-protonated proline-containing peptides with N-terminal arginine are photodissociated with vacuum ultraviolet (VUV) light in an ESI linear ion trap/orthogonal-TOF (LIT/o-TOF). When proline is the nth residue from the N-terminus, unusual b(n) + 2 and a(n) + 2 ions are observed. Their formation is explained by homolytic cleavage of the C(alpha)-C bond in conjunction with a rearrangement of ...
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ژورنال
عنوان ژورنال: Journal of the American Society for Mass Spectrometry
سال: 1993
ISSN: 1044-0305,1879-1123
DOI: 10.1016/1044-0305(93)85087-e